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A reason for this behaviour could be that H 2 O 2 does not oxidize GSH directly, but rather through the action of glutathione peroxidase 26

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S-Acetyl-L-glutathione: Physiological Roles and Pharmacokinetic Characteristics Mar 19, 2024 S-Acetyl-L-glutathione enhances GSH levels, stability, and absorption, showing potential in oxidative stress management and cancer therapy