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And the physical barrier is, is a particle size barrier

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In the oxidative phosphorylation pathway, metabolites of glutamine participate in the generation of an electron donor, such as NADH or FADH 2 , after synthesis of guanosine triphosphate (GTP) and adenosine triphosphate (ATP)

J Biol Chem 282 , 2566825676, doi: M702076200 [pii]10.1074/jbc.M702076200 (2007)

The gain-of-function of mutant SOD1 toxicity has been also related to its ability to generate oxidants, as well as to a higher sensitivity of the enzyme to oxidants